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Ah, so they're Hsiung Feng III missiles.
A 'self-forging fragment' is another term for an explosively-formed penetrator. Basically, it's a type of shaped charge that, on detonation, deforms a metal plate into a slug that slams into the target. Not the best for anti-personnel use, although...
It might well be the latter, on the basis that even though he originally took the name basically as a joke, by this point, after all this time and everything that has happened (not least nomming the soul of the Original Flavour) he is Grayven.
I think the reasonable presumption would be "if it has desires, it can be Assimilated."
Whether or not the ring holds enough charge to complete the process before it runs out, of course, being the outstanding open question.
It's amusing to me that Selina calls Riddler "Eddie", but uses Cluemaster's nom de cape instead of calling him "Arthur". It's a good hint that Riddler is more part of the main Gotham Villains Social Circle than Cluemaster is.